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We are grateful to the National Basic Research Program of China (973 Program, grant no. 2010CB833200), the Chinese Academy of Sciences, the National Natural Science Foundation of China (grant no. 20632050 and 20921091) for their financial support.
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Communication
A Convergent Route to the Galbulimima Alkaloids (−)-GB 13 and (+)-GB 16†
Article first published online: 13 JUL 2010
DOI: 10.1002/anie.201002299
Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Zi, W., Yu, S. and Ma, D. (2010), A Convergent Route to the Galbulimima Alkaloids (−)-GB 13 and (+)-GB 16. Angewandte Chemie International Edition, 49: 5887–5890. doi: 10.1002/anie.201002299
- †
Publication History
- Issue published online: 30 JUL 2010
- Article first published online: 13 JUL 2010
- Manuscript Received: 19 APR 2010
Funded by
- National Basic Research Program of China. Grant Number: 2010CB833200
- Chinese Academy of Sciences
- National Natural Science Foundation of China. Grant Numbers: 20632050, 20921091
Keywords:
- alkaloids;
- Michael addition;
- natural products;
- reductive coupling;
- total synthesis
Graphical Abstract
Alkaloids all round: A 19-step total synthesis of the galbulimima alkaloid (−)-GB 13 starting from commercially available starting material and the first total synthesis of the galbulimima alkaloid (+)-GB 16 have been achieved (see scheme; Boc=tert-butoxycarbonyl).