Communication

Platinum and Palladium Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation†

  1. Marion H. Emmert Dr.,
  2. J. Brannon Gary,
  3. Janette M. Villalobos Dr.,
  4. Melanie S. Sanford Prof.

Article first published online: 15 JUL 2010

DOI: 10.1002/anie.201002351

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 49, Issue 34, pages 5884–5886, August 9, 2010

Additional Information

How to Cite

Emmert, Marion H., Gary, J. Brannon., Villalobos, Janette M. and Sanford, Melanie S. (2010), Platinum and Palladium Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation. Angew. Chem. Int. Ed., 49: 5884–5886. doi: 10.1002/anie.201002351

Author Information

  1. Department of Chemistry, University of Michigan, 930 N. University Ave, Ann Arbor, MI 48109 (USA), Fax: (+1) 734-647-4865

  1. †

    We thank the NSF for support of this work through the Center for Enabling New Technologies through Catalysis. M.H.E. thanks the DFG (German Research Council) for a postdoctoral fellowship (EM 219/1-1). J.B.G. thanks the NSF for a predoctoral fellowship.

Publication History

  1. Issue published online: 30 JUL 2010
  2. Article first published online: 15 JUL 2010
  3. Manuscript Revised: 1 JUN 2010
  4. Manuscript Received: 20 APR 2010

Funded by

  • NSF
  • DFG

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (371K)

Keywords:

  • C[BOND]H activation;
  • H/D exchange;
  • ligand design;
  • oxidation;
  • platinum
Thumbnail image of graphical abstract

Cationic catalysts in HD: Palladium(II) and platinum(II) complexes of pyridinium-substituted bipyridine ligands are highly active and stable catalysts for H/D exchange and oxidation of aromatic C[BOND]H bonds (TONs up to 3200, TOFs up to 0.1 s−1; see scheme, EWG=electron-withdrawing group, EDG=electron-donating group).

View Full Article with Supporting Information (HTML) Get PDF (371K)