SEARCH

SEARCH BY CITATION

Keywords:

  • asymmetric catalysis;
  • cascade reactions;
  • cycloaddition;
  • Diels–Alder reaction;
  • rhodium
Thumbnail image of graphical abstract

Bridging a gap: A cationic rhodium(I)/ligand complex catalyzes the title reaction of alkynes and amide-linked 1,5-dienes, leading to bridged multicyclic compounds, with high chemo-, regio-, and enantioselectivity (see scheme; Bn=benzyl).