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Keywords:

  • carbonyl ligands;
  • enzyme models;
  • [Fe]-hydrogenase;
  • pyridine ligands;
  • trans influence
Thumbnail image of graphical abstract

Where is my iron? The synthesis, structure, and reactivity of small-molecule models of [Fe]-hydrogenase are described. These models feature the intriguing acylmethylpyridinyl ligands found exclusively in the enzyme.