SEARCH

SEARCH BY CITATION

Keywords:

  • iron complexes;
  • metal cluster;
  • polyamide ligand;
  • polynuclear complexes;
  • redox reactions
Thumbnail image of graphical abstract

A modular hexadentate polyamide ligand directs the assembly of triiron complexes (see structure). Crystallographic studies reveal significant metal–metal bonding interactions, which are enhanced upon oxidation.