Towards Polycyclic Aromatic Hydrocarbons with a Singlet Open-Shell Ground State


  • Prof. Dr. Christoph Lambert

    Corresponding author
    1. Institut für Organische Chemie
    2. Wilhelm Conrad Röntgen Research Center for Complex Material Systems (RCCM), Universität Würzburg, Am Hubland, 97074 Würzburg (Germany), Fax: (+49) 931-31-87218
    • Institut für Organische Chemie
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Teranthene—a molecular section of graphene: The surprising stability of teranthene at ambient conditions allowed its characterization, which pointed toward a high biradical contribution in the singlet ground state (see scheme). Polycyclic aromatic hydrocarbons with high singlet biradical character show high third-order nonlinear optical properties, which makes them interesting candidates for (opto)electronic devices.