The authors gratefully acknowledge the University of Denver for funding.
Efficient Loading and Kinetic Trapping of Hexameric Pyrogallolarene Capsules in Solution†
Article first published online: 1 FEB 2011
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 50, Issue 10, pages 2244–2248, March 1, 2011
How to Cite
Kvasnica, M., Chapin, J. C. and Purse, B. W. (2011), Efficient Loading and Kinetic Trapping of Hexameric Pyrogallolarene Capsules in Solution. Angew. Chem. Int. Ed., 50: 2244–2248. doi: 10.1002/anie.201007800
- Issue published online: 24 FEB 2011
- Article first published online: 1 FEB 2011
- Manuscript Received: 10 DEC 2011
- University of Denver
- host–guest systems;
- supramolecular chemistry
Solvent matters: By carrying out the assembly of pyrogallolarene hexamers under thermal conditions in the absence of solvent, highly efficient loading of guest molecules to produce kinetically trapped assemblies was achieved. Such products are not formed when the solvents are present (see schematic).