Catalytic and Direct Oxyphosphorylation of Alkenes with Dioxygen and H-Phosphonates Leading to β-Ketophosphonates

Authors

  • Wei Wei,

    1. Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, 610041 (China)
    2. Graduate School of Chinese Academy of Sciences, Beijing, 100049 (China)
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  • Prof. Dr. Jian-Xin Ji

    Corresponding author
    1. Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, 610041 (China)
    • Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, 610041 (China)
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  • We are grateful for the financial support from the Natural Science Foundation of China (20802072).

Abstract

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Direct access: The title reaction has been developed under mild reaction conditions (see scheme; DMSO=dimethyl sulfoxide). This reaction can be effectively scaled up and offers not only a green and attractive approach to β-ketophosphonates, but also a useful example of direct incorporation of an oxygen atom from dioxygen into organic frameworks.

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