We are grateful for the financial support from the Natural Science Foundation of China (20802072).
Catalytic and Direct Oxyphosphorylation of Alkenes with Dioxygen and H-Phosphonates Leading to β-Ketophosphonates†
Article first published online: 24 AUG 2011
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 50, Issue 39, pages 9097–9099, September 19, 2011
How to Cite
Wei, W. and Ji, J.-X. (2011), Catalytic and Direct Oxyphosphorylation of Alkenes with Dioxygen and H-Phosphonates Leading to β-Ketophosphonates. Angew. Chem. Int. Ed., 50: 9097–9099. doi: 10.1002/anie.201100219
- Issue published online: 15 SEP 2011
- Article first published online: 24 AUG 2011
- Manuscript Revised: 1 JUN 2011
- Manuscript Received: 11 JAN 2011
- Natural Science Foundation of China. Grant Number: 20802072
- homogeneous catalysis;
- synthetic methods
Direct access: The title reaction has been developed under mild reaction conditions (see scheme; DMSO=dimethyl sulfoxide). This reaction can be effectively scaled up and offers not only a green and attractive approach to β-ketophosphonates, but also a useful example of direct incorporation of an oxygen atom from dioxygen into organic frameworks.