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Reactivity of a Scandium Terminal Imido Complex Towards Unsaturated Substrates

Authors

  • Jiaxiang Chu,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032 (P. R. China)
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  • Erli Lu,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032 (P. R. China)
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  • Zhixiao Liu,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032 (P. R. China)
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  • Prof. Dr. Yaofeng Chen,

    Corresponding author
    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032 (P. R. China)
    • State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032 (P. R. China)
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  • Dr. Xuebing Leng,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032 (P. R. China)
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  • Dr. Haibin Song

    1. State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071 (P. R. China)
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  • This work was supported by the National Natural Science Foundation of China (Grant Nos. 20821002 and 21072209) and Chinese Academy of Sciences.

Abstract

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A complex complex: The reactions of a scandium terminal imido complex with a series of unsaturated substrates, including CO2, PhCN, methyl methacrylate (MMA), cyclopentadiene, PhNCO, and propylene oxide, are presented (see scheme). A variety of intriguing products are formed from this complex. Ar=2,6-(iPr)2C6H3.

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