We thank Prof. Dr. H. Waldmann for his generous support.
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Communication
Organocatalytic, Oxidative, Intramolecular C![[BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif)
H Bond Amination and Metal-free Cross-Amination of Unactivated Arenes at Ambient Temperature†
Article first published online: 26 JUL 2011
DOI: 10.1002/anie.201102984
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Issue
Angewandte Chemie International Edition
Volume 50, Issue 37, pages 8605–8608, September 5, 2011
Additional Information
How to Cite
Antonchick, A. P., Samanta, R., Kulikov, K. and Lategahn, J. (2011), Organocatalytic, Oxidative, Intramolecular CH Bond Amination and Metal-free Cross-Amination of Unactivated Arenes at Ambient Temperature. Angewandte Chemie International Edition, 50: 8605–8608. doi: 10.1002/anie.201102984
- †
Publication History
- Issue published online: 1 SEP 2011
- Article first published online: 26 JUL 2011
- Manuscript Revised: 25 MAY 2011
- Manuscript Received: 30 APR 2011
Keywords:
- amination;
- CH functionalization;
- hypervalent compounds;
- iodine;
- organocatalysis
Graphical Abstract
The twinkling of an I: In a new atom-economical and environmentally friendly organocatalytic method for intramolecular CH amination, the CN bond forms at ambient temperature by abstraction of two atoms of hydrogen; only acetic acid and water are formed as by-products. The method has also been extended to the unprecedented metal-free cross-amination of nonactivated arenes.