Communication

Highly Regio- and Stereoselective Synthesis of Multialkylated Olefins through Carbozirconation of Alkynylboronates and Sequential Negishi and Suzuki–Miyaura Coupling Reactions†

  1. Prof. Dr. Yasushi Nishihara*,
  2. Yoshiaki Okada,
  3. Jiao Jiao,
  4. Masato Suetsugu,
  5. Ming-Tzu Lan,
  6. Megumi Kinoshita,
  7. Prof. Dr. Masayuki Iwasaki,
  8. Prof. Dr. Kentaro Takagi

Article first published online: 9 AUG 2011

DOI: 10.1002/anie.201103601

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 50, Issue 37, pages 8660–8664, September 5, 2011

Additional Information

How to Cite

Nishihara, Y., Okada, Y., Jiao, J., Suetsugu, M., Lan, M.-T., Kinoshita, M., Iwasaki, M. and Takagi, K. (2011), Highly Regio- and Stereoselective Synthesis of Multialkylated Olefins through Carbozirconation of Alkynylboronates and Sequential Negishi and Suzuki–Miyaura Coupling Reactions. Angew. Chem. Int. Ed., 50: 8660–8664. doi: 10.1002/anie.201103601

Author Information

  1. Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530 (Japan)

*Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530 (Japan)

  1. †

    We gratefully thank Prof. Hiroshi Nakazawa and Dr. Masumi Itazaki at Osaka City University for measurements of elemental analyses and Prof. Tamotsu Takahashi at Hokkaido University for generous donation of zirconocene dichloride. This work was supported by a Grant-in-Aid for Scientific Research on Priority Areas “Advanced Molecular Transformations of Carbon Resources” from the Ministry of Education, Culture, Sports, Science and Technology (Japan).

Publication History

  1. Issue published online: 1 SEP 2011
  2. Article first published online: 9 AUG 2011
  3. Manuscript Received: 26 MAY 2011

Funded by

  • Grant-in-Aid for Scientific Research
  • Ministry of Education, Culture, Sports, Science and Technology

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View Full Article with Supporting Information (HTML) Get PDF (327K)