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Periodic Mesoporous Organosilica Derivatives Bearing a High Density of Metal Complexes on Pore Surfaces



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Periodic mesoporous organosilica derivatives (PMOs) that bear a high density of Ru and Ir complexes on pore walls were synthesized using a unique two-step approach: 1) synthesis of PMO containing phenylpyridine bridging groups in the pore walls, and 2) post-synthetic formation of metal complexes using the phenylpyridine groups as chelating ligands (see picture).

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