Communication

Enantiopure Metal–Organic Framework Thin Films: Oriented SURMOF Growth and Enantioselective Adsorption†

  1. Dr. Bo Liu1,
  2. Dr. Osama Shekhah2,
  3. Hasan K. Arslan2,
  4. Dr. Jinxuan Liu2,
  5. Prof. Dr. Christof Wöll2,*,
  6. Prof. Dr. Roland A. Fischer1,*

Article first published online: 3 NOV 2011

DOI: 10.1002/anie.201104240

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 51, Issue 3, pages 807–810, January 16, 2012

Additional Information

How to Cite

Liu, B., Shekhah, O., Arslan, H. K., Liu, J., Wöll, C. and Fischer, R. A. (2012), Enantiopure Metal–Organic Framework Thin Films: Oriented SURMOF Growth and Enantioselective Adsorption. Angew. Chem. Int. Ed., 51: 807–810. doi: 10.1002/anie.201104240

Author Information

  1. 1

    Chair of Inorganic Chemistry II—, Organometallics and Materials Chemistry, Ruhr-Universität Bochum, 44870 Bochum (Germany)

  2. 2

    Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344 Karlsruhe (Germany)

*Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344 Karlsruhe (Germany)

  1. †

    This work was funded within the priority program of the German Research Foundation (DFG) on Metal–Organic Frameworks (SPP 1362). B.L. is grateful for a stipend from the Alexander von Humboldt Foundation. SURMOFs=surface-mounted metal–organic frameworks.

Publication History

  1. Issue published online: 12 JAN 2012
  2. Article first published online: 3 NOV 2011
  3. Manuscript Revised: 27 JUL 2011
  4. Manuscript Received: 20 JUN 2011

Funded by

  • German Research Foundation (DFG)
  • Alexander von Humboldt Foundation

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Keywords:

  • enantioselective adsorption;
  • enantiopure metal–organic frameworks;
  • quartz crystal microbalance;
  • surface chemistry;
  • thin films
Thumbnail image of graphical abstract

Stuck on you: Preferred (110) and (001) orientation of enantiopure [{Zn2((+)cam)2(dabco)}n] ((+)cam=(1R,3S)-(+)-camphoric acid, dabco=1,4-diazabicyclo(2.2.2)octane) thin films can be controlled by carboxylate and pyridyl groups on self-assembled monolayers (SAMs). With a quartz crystal microbalance, the enantioselective adsorption of enantiomeric hexanediol pairs by enantiopure surface-attached metal–organic frameworks (SURMOF) [Zn2((±)cam)2(dabco)] pairs can be demonstrated (see picture).

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