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Well-Defined Soluble P3−-Containing Rare-Earth-Metal Compounds

Authors

  • Yingdong Lv,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032 (P.R. China)
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  • Xin Xu,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032 (P.R. China)
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  • Prof. Dr. Yaofeng Chen,

    Corresponding author
    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032 (P.R. China)
    • State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032 (P.R. China)
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  • Dr. Xuebing Leng,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032 (P.R. China)
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  • Prof. Dr. Maxim V. Borzov

    1. College of Chemistry and Material Science, The North-West University of Xi'an, 229 Taibai Bei Road, Xi'an, Shaanxi prov. 710069 (P.R. China)
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  • This work was supported by the National Natural Science Foundation of China (grant Nos. 20872164 and 20821002), the State Key Basic Research & Development Program (grant No. 2011CB808705), Shanghai Municipal Committee of Science and Technology (10DJ1400104), and Chinese Academy of Sciences.

Abstract

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A rare find: Soluble P3−-containing rare-earth-metal coordination compounds have been synthesized. A P3−-containing polymetallic yttrium iodide was obtained through P[BOND]Si (or H) and P[BOND]C bond cleavage, and this compound can be transferred into other P3−-containing yttrium coordination compounds by metathesis reactions.

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