A.J.R. acknowledges support from a EU Marie-Curie IIF Fellowship (PIIF-GA-2010-274574). Financial support is acknowledged from EQUIPEX contract ANR-10-EQPX-47-01, and the ETH Zürich.
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Communication
Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy of Functionalized Metal–Organic Frameworks†
Article first published online: 15 NOV 2011
DOI: 10.1002/anie.201106030
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Rossini, A. J., Zagdoun, A., Lelli, M., Canivet, J., Aguado, S., Ouari, O., Tordo, P., Rosay, M., Maas, W. E., Copéret, C., Farrusseng, D., Emsley, L. and Lesage, A. (2012), Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy of Functionalized Metal–Organic Frameworks. Angew. Chem. Int. Ed., 51: 123–127. doi: 10.1002/anie.201106030
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Publication History
- Issue published online: 29 DEC 2011
- Article first published online: 15 NOV 2011
- Manuscript Received: 25 AUG 2011
Funded by
- EU. Grant Number: PIIF-GA-2010-274574
- EQUIPEX. Grant Number: ANR-10-EQPX-47-01
- ETH Zürich
Keywords:
- dynamic nuclear polarization;
- hyperpolarization;
- metal–organic frameworks;
- solid-state NMR spectroscopy
A matter of minutes: Dynamic nuclear polarization (DNP) is applied to enhance the signal of solid-state NMR spectra of metal–organic framework (MOF) materials. The signal enhancement enables the acquisition of high-quality 1D 13C solid-state NMR spectra, 2D 1H–13C dipolar HETCOR and 1D 15N solid-state NMR spectra with natural isotopic abundance in experiment times on the order of minutes. MW=microwaves.