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Direct Preparation of Sulfide Semiconductor Nanoparticles from the Corresponding Bulk Powders in an Ionic Liquid

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  • The authors acknowledge Xunta de Galicia (Consellería de Industria e Innovación) for financial support through project 10REM265008PR, and Cytec for the kind donation of the ionic liquid [P6 6 6 14]Cl. B. R. and H. R. are grateful to Ministry for Science and Innovation of Spain, for the award of an FPI grant (ref. BES-2010-033448) and for support through the “Ramón y Cajal” program, respectively.

Abstract

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Just add liquid and stir: Dispersions of metal sulfide nanoparticles (CdS, ZnS, PbS, and MnS) can be prepared directly by mixing the corresponding bulk solid with an appropriate ionic liquid, without further additives or solvents (see scheme). The selection of the ionic liquid is critical for the viability of this nanoparticle preparation method.

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