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Keywords:

  • auto-healing;
  • cyclodextrins;
  • host–guest systems;
  • polyoxometalates
Thumbnail image of graphical abstract

You'll never walk alone: An auto-healing process of the first host–guest complex involving a polyoxometalate hybrid and a cyclodextrin is reported. Indeed, this inclusion complex allows the complete restoration of the anchored organic moiety released by a basic stress, a process otherwise not fully reversible.