• Please log in or register to access this feature.

Communication

Reagent-Installed Capsule Network: Selective Thiocarbamoylation of Aromatic Amines in Crystals with Preinstalled CH3NCS†

  1. Dr. Yasuhide Inokuma,
  2. Guo-Hong Ning,
  3. Prof. Dr. Makoto Fujita*

Article first published online: 19 JAN 2012

DOI: 10.1002/anie.201107190

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 51, Issue 10, pages 2379–2381, March 5, 2012

Additional Information

How to Cite

Inokuma, Y., Ning, G.-H. and Fujita, M. (2012), Reagent-Installed Capsule Network: Selective Thiocarbamoylation of Aromatic Amines in Crystals with Preinstalled CH3NCS. Angew. Chem. Int. Ed., 51: 2379–2381. doi: 10.1002/anie.201107190

Author Information

  1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

*Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

  1. †

    This research was supported by the CREST project of the Japan Science and Technology Agency (JST), for which M.F. is the principal investigator, and also in part by KAKENHI (20044006), JSPS, and Global COE Program (Chemistry Innovation through Cooperation of Science and Engineering), MEXT (Japan). Y.I. thanks Kurata Grants for younger scientists.

Publication History

  1. Issue published online: 1 MAR 2012
  2. Article first published online: 19 JAN 2012
  3. Manuscript Received: 11 OCT 2011

Funded by

  • Japan Science and Technology Agency (JST)
  • KAKENHI. Grant Number: 20044006
  • JSPS
  • Global COE Program
  • MEXT

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (833K)

Keywords:

  • host–guest systems;
  • molecular capsules;
  • porous coordination networks;
  • solid-state reactions;
  • synthetic methods
Thumbnail image of graphical abstract

Crystalline reagent capsules were prepared by installing CH3NCS into networked molecular capsules. While the tight encapsulation completely prevented leaching of reagent molecules into the supernatant, introduction of amines into the interstitial pores triggered reagent delivery. As a result, enhanced substrate selectivity was observed in crystalline-state thiocarbamoylation (see picture; 86:14 in favor of 2- vs. 1-naphthylamine).

View Full Article with Supporting Information (HTML) Get PDF (833K)