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Porous Single-Crystalline Palladium Nanoparticles with High Catalytic Activities

Authors

  • Feng Wang,

    1. State Key Lab of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871 (China)
    2. Department of Physics, The Chinese University of Hong Kong, Shatin, Hong Kong SAR (China)
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  • Chuanhao Li,

    1. Department of Chemistry, The Chinese University of Hong Kong, Shatin, Hong Kong SAR (China)
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  • Prof. Ling-Dong Sun,

    Corresponding author
    1. State Key Lab of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871 (China)
    • State Key Lab of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871 (China)
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  • Chun-Hu Xu,

    1. State Key Lab of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871 (China)
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  • Prof. Jianfang Wang,

    Corresponding author
    1. Department of Physics, The Chinese University of Hong Kong, Shatin, Hong Kong SAR (China)
    • Department of Physics, The Chinese University of Hong Kong, Shatin, Hong Kong SAR (China)
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  • Prof. Jimmy C. Yu,

    1. Department of Chemistry, The Chinese University of Hong Kong, Shatin, Hong Kong SAR (China)
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  • Prof. Chun-Hua Yan

    Corresponding author
    1. State Key Lab of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871 (China)
    • State Key Lab of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871 (China)
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  • This work was supported by the National Natural Science Foundation of China (Project Code: 20931160429) and the Research Grants Council of Hong Kong (NSFC/RGC Joint Scheme, Ref.: N_CUHK465/09, Project Code: 2900339; Direct Allocation, Project Code: 2060417).

Abstract

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Palladium's pore cousin: A facile approach is described for the size-controlled preparation of porous single-crystalline Pd nanoparticles. These porous Pd nanoparticles exhibit size-independent catalytic activities for the Suzuki coupling and are more active than commercial Pd/C catalysts.

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