Communication

The 1,1-Carboboration of Bis(alkynyl)phosphanes as a Route to Phosphole Compounds†

  1. Juri Möbus1,
  2. Quentin Bonnin1,
  3. Kirika Ueda1,2,
  4. Dr. Roland Fröhlich1,
  5. Prof. Kenichiro Itami2,
  6. Dr. Gerald Kehr1,
  7. Gerhard Erker1,*

Article first published online: 13 JAN 2012

DOI: 10.1002/anie.201107398

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 51, Issue 8, pages 1954–1957, February 20, 2012

Additional Information

How to Cite

Möbus, J., Bonnin, Q., Ueda, K., Fröhlich, R., Itami, K., Kehr, G. and Erker, G. (2012), The 1,1-Carboboration of Bis(alkynyl)phosphanes as a Route to Phosphole Compounds. Angew. Chem. Int. Ed., 51: 1954–1957. doi: 10.1002/anie.201107398

Author Information

  1. 1

    Organisch-Chemisches Institut der Universität Münster, Corrensstrasse 40, 48149 Münster (Germany)

  2. 2

    Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602 (Japan)

*Organisch-Chemisches Institut der Universität Münster, Corrensstrasse 40, 48149 Münster (Germany)

  1. †

    Financial support from the Deutsche Forschungsgemeinschaft is gratefully acknowledged. J.M. thanks the NRW Research School (University Münster) for a stipend. K.U. thanks JSPS and the International Research Training Group Münster/Nagoya for fellowship and support.

Publication History

  1. Issue published online: 14 FEB 2012
  2. Article first published online: 13 JAN 2012
  3. Manuscript Received: 20 OCT 2011

Funded by

  • Deutsche Forschungsgemeinschaft
  • NRW Research School (University Münster)
  • JSPS
  • International Research Training Group Münster/Nagoya

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (414K)

Keywords:

  • boranes;
  • carboboration;
  • cross-coupling;
  • phospholes
Thumbnail image of graphical abstract

Neat and tidy: B(C6F5)3 efficiently converts a series of bis(alkynyl)phosphanes into highly substituted 3-borylphospholes through a twofold 1,1-carboboration reaction sequence. The boron substituted phospholes were also used as substrates in Suzuki–Miyaura type cross-coupling reactions (see scheme).

View Full Article with Supporting Information (HTML) Get PDF (414K)