This work was sponsored by the Materials Sciences and Engineering Division (Z.A.Q., J.A., G.M.V., R.R.U., S.D.) and the Division of Chemical Sciences, Geosciences, and Biosciences (S.B., J.C.B.), Office of Basic Energy Sciences, US Department of Energy. A portion of this research was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Office of Basic Energy Sciences, US Department of Energy. Microscopy was supported by ORNL’s Shared Research Equipment (SHaRE) User Facility, which is sponsored by the Office of Basic Energy Sciences, US Department of Energy.
A Topotactic Synthetic Methodology for Highly Fluorine-Doped Mesoporous Metal Oxides†
Article first published online: 6 FEB 2012
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 51, Issue 12, pages 2888–2893, March 19, 2012
How to Cite
Qiao, Z.-a., Brown, S. S., Adcock, J., Veith, G. M., Bauer, J. C., Payzant, E. A., Unocic, R. R. and Dai, S. (2012), A Topotactic Synthetic Methodology for Highly Fluorine-Doped Mesoporous Metal Oxides . Angew. Chem. Int. Ed., 51: 2888–2893. doi: 10.1002/anie.201107812
- Issue published online: 13 MAR 2012
- Article first published online: 6 FEB 2012
- Manuscript Revised: 9 DEC 2011
- Manuscript Received: 6 NOV 2011
- Office of Basic Energy Sciences, US Department of Energy
- mesoporous materials;
- synthetic methods
F tactic: Highly fluorine-doped mesoporous metal oxides (up to 40 atom %) were synthesized by topotactic fluorination synthesis with mesoporous metal oxides as starting materials and fluorine as the fluorination agent. The surface areas, pore sizes, pore volumes, and F atomic concentrations of these materials could be adjusted over a wide range by varying the fluorination time and temperature.