• Please log in or register to access this feature.

Communication

Kinetic Resolution of Planar-Chiral (η6-Arene)Chromium Complexes by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis†

  1. Prof. Masamichi Ogasawara1,*,
  2. Dr. Wei-Yi Wu2,
  3. Sachie Arae1,
  4. Dr. Susumu Watanabe1,
  5. Tomotaka Morita2,
  6. Prof. Tamotsu Takahashi1,*,
  7. Prof. Ken Kamikawa2,*

Article first published online: 3 FEB 2012

DOI: 10.1002/anie.201108292

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 51, Issue 12, pages 2951–2955, March 19, 2012

Additional Information

How to Cite

Ogasawara, M., Wu, W.-Y., Arae, S., Watanabe, S., Morita, T., Takahashi, T. and Kamikawa, K. (2012), Kinetic Resolution of Planar-Chiral (η6-Arene)Chromium Complexes by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis . Angew. Chem. Int. Ed., 51: 2951–2955. doi: 10.1002/anie.201108292

Author Information

  1. 1

    Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita-ku, Sapporo 001-0021 (Japan)

  2. 2

    Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan)

*Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Kita-ku, Sapporo 001-0021 (Japan)

  1. †

    This work was supported by the Cooperative Research Program of the Catalysis Research Center, Hokkaido University (Grant no. 10A0002 and no. 11A0003) and a Grant-in-Aid for Scientific Research on Innovative Areas to M.O. and K.K. from MEXT (Japan).

Publication History

  1. Issue published online: 13 MAR 2012
  2. Article first published online: 3 FEB 2012
  3. Manuscript Revised: 2 JAN 2012
  4. Manuscript Received: 24 NOV 2011

Funded by

  • Hokkaido University. Grant Numbers: 10A0002, 11A0003
  • MEXT (Japan)

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (407K)

Keywords:

  • asymmetric synthesis;
  • chirality;
  • chromium;
  • kinetic resolution;
  • metathesis
Thumbnail image of graphical abstract

Molybdenum-catalyzed asymmetric ring-closing metathesis has been used for the kinetic resolution of racemic planar-chiral (η6-arene)chromium complexes with excellent enantioselectivity. The products are excellent precursors for the synthesis of various planar-chiral (η6-arene)chromium derivatives and can also be applied as chiral ligands in rhodium-catalyzed asymmetric reactions.

View Full Article with Supporting Information (HTML) Get PDF (407K)