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Keywords:

  • boranes;
  • cyclizations;
  • hydrogen;
  • ruthenium;
  • synthetic methods
Thumbnail image of graphical abstract

Remote control: The title reaction is the first example of a catalyzed dehydrogenative cyclization (CDC) of diamine–monoboranes to give cyclic diaminoboranes. The cyclization reaction is strongly dependent on the nature of the substitution pattern at the remote amino group.