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Keywords:

  • asymmetric catalysis;
  • heterogeneous catalysis;
  • organocatalysis;
  • phosphorus;
  • porous polymers
Thumbnail image of graphical abstract

No slow down: A microporous recyclable heterogeneous catalyst made from a 1,1′-binaphthalene-2,2′-diol (binol)-derived phosphoric acid chloride is as active as the corresponding homogeneous catalyst when using the same mass of both in different reactions. Reaction rates, yields, and enantioselectivities are comparable.