Communication

The First Borosulfate K5[B(SO4)4]

  1. Prof. Dr. Henning A. Höppe1,*,
  2. Dr. Karolina Kazmierczak1,
  3. Michael Daub2,
  4. Katharina Förg1,
  5. Franziska Fuchs1,
  6. Prof. Dr. Harald Hillebrecht2

Article first published online: 8 MAY 2012

DOI: 10.1002/anie.201109237

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 51, Issue 25, pages 6255–6257, June 18, 2012

Additional Information

How to Cite

Höppe, H. A., Kazmierczak, K., Daub, M., Förg, K., Fuchs, F. and Hillebrecht, H. (2012), The First Borosulfate K5[B(SO4)4]. Angew. Chem. Int. Ed., 51: 6255–6257. doi: 10.1002/anie.201109237

Author Information

  1. 1

    Institut für Physik, Universität Augsburg, Universitätsstrasse 1, 86159 Augsburg (Germany) http://www.ak-hoeppe.de

  2. 2

    Institut für Anorganische und Analytische Chemie, Albert-Ludwigs-Universität Freiburg, Albertstrasse 21, 79104 Freiburg (Germany)

*Institut für Physik, Universität Augsburg, Universitätsstrasse 1, 86159 Augsburg (Germany) http://www.ak-hoeppe.de

Publication History

  1. Issue published online: 13 JUN 2012
  2. Article first published online: 8 MAY 2012
  3. Manuscript Received: 29 DEC 2012
  4. Manuscript Revised: 28 FEB 2012

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Keywords:

  • borosulfates;
  • potassium;
  • structure elucidation;
  • sulfates;
  • sulfur
Thumbnail image of graphical abstract

The first of its kind: K5[B(SO4)4], the first example of a borosulfate, comprises non-condensed [B(SO4)4]5− anions in which the boron atoms are tetrahedrally coordinated to sulfate tetrahedra (see picture; B brown, O red, S yellow). The compound, which crystallizes in a polar space group, was investigated by X-ray diffraction, vibrational spectroscopy, and calculations.

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