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Keywords:

  • ambiphilic ligands;
  • bismuth;
  • gold;
  • metallophilic interactions;
  • platinum
Thumbnail image of graphical abstract

Noble metals meet a heavyweight: A pincer ligand brings together bismuth with gold and platinum, so that metallophilic interactions are established. According to DFT calculations, these interactions contain dominant metal[RIGHTWARDS ARROW]bismuth contributions.