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Keywords:

  • C[BOND]H activation;
  • gas-phase reactions;
  • mass spectrometry;
  • radicals
Thumbnail image of graphical abstract

HAT in hand: The heteronuclear oxide cluster YAlO3+. exhibits higher reactivity and selectivity than Y2O3+. and Al2O3+., respectively, in the reaction with methane by hydrogen-atom transfer (HAT) at room temperature (see scheme).