Communication

An Energy Storage Principle using Bipolar Porous Polymeric Frameworks†

  1. Ken Sakaushi1,2,*,
  2. Georg Nickerl2,
  3. Florian M. Wisser2,
  4. Dr. Daisuke Nishio-Hamane4,
  5. Dr. Eiji Hosono5,
  6. Prof. Dr. Haoshen Zhou5,*,
  7. Prof. Dr. Stefan Kaskel2,
  8. Prof. Dr. Jürgen Eckert1,3

Article first published online: 21 JUN 2012

DOI: 10.1002/anie.201202476

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 51, Issue 31, pages 7850–7854, July 27, 2012

Additional Information

How to Cite

Sakaushi, K., Nickerl, G., Wisser, F. M., Nishio-Hamane, D., Hosono, E., Zhou, H., Kaskel, S. and Eckert, J. (2012), An Energy Storage Principle using Bipolar Porous Polymeric Frameworks . Angew. Chem. Int. Ed., 51: 7850–7854. doi: 10.1002/anie.201202476

Author Information

  1. 1

    Institute for Complex Materials, IFW Dresden, Helmholtzstrasse 20, 01069 Dresden (Germany)

  2. 2

    Department of Inorganic Chemistry, TU Dresden (Germany)

  3. 3

    Institute of Materials Science, TU Dresden (Germany)

  4. 4

    Institute for Solid State Physics (ISSP), The University of Tokyo (Japan)

  5. 5

    Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST) (Japan)

*Institute for Complex Materials, IFW Dresden, Helmholtzstrasse 20, 01069 Dresden (Germany)

  1. †

    We are grateful to Prof. Dr. T. Kudo (AIST/Univ. Tokyo) for his valuable comments. We thank for Dr. S. Pauly, Dr. P. Dunne, and members of their laboratories. This work was partially performed using facilities of ISSP (Univ. Tokyo). K.S. is supported by DAAD under the grant number of A/09/74990.

Publication History

  1. Issue published online: 25 JUL 2012
  2. Article first published online: 21 JUN 2012
  3. Manuscript Received: 30 MAR 2012

Funded by

  • DAAD. Grant Number: A/09/74990

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (1227K)

Keywords:

  • amorphous materials;
  • bipolarity;
  • energy storage;
  • polymeric frameworks;
  • porous materials
Thumbnail image of graphical abstract

Packed with energy: Amorphous covalent triazine-based frameworks were used as a cathode material, with the aim of developing an energy storage principle that can deliver a 2–3 times higher specific energy than current batteries with a high rate capability. The material undergoes a unique Faradaic reaction, as it can be present in both a p-doped and an n-doped state (see picture).

View Full Article with Supporting Information (HTML) Get PDF (1227K)