Financial support is provided by NNSFC (Nos. 20972003, 21132007) and MOST (No. 2011CB808401).
Fullerene Doping: Preparation of Azafullerene C59NH and Oxafulleroids C59O3 and C60O4†
Article first published online: 9 MAY 2012
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 51, Issue 25, pages 6163–6166, June 18, 2012
How to Cite
Xin, N., Huang, H., Zhang, J., Dai, Z. and Gan, L. (2012), Fullerene Doping: Preparation of Azafullerene C59NH and Oxafulleroids C59O3 and C60O4 . Angew. Chem. Int. Ed., 51: 6163–6166. doi: 10.1002/anie.201202777
- Issue published online: 13 JUN 2012
- Article first published online: 9 MAY 2012
- Manuscript Received: 11 APR 2012
- NNSFC. Grant Numbers: 20972003, 21132007
- MOST. Grant Number: 2011CB808401
- gas-phase reactions;
Breaking the surface: Replacement of a fullerene cage carbon with a nitrogen or oxygen atom is achieved by reactions mediated with fullerene peroxide. Similar procedures have also generated oxafulleroids with oxygen atoms inserted into the cage skeleton. The dioxafullerene C58O2 was selectively generated in the gas phase under MALDI-TOF conditions.