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Communication

Low-Energy Selective Capture of Carbon Dioxide by a Pre-designed Elastic Single-Molecule Trap†

  1. Dr. Mario Wriedt1,
  2. Julian P. Sculley1,
  3. Andrey A. Yakovenko1,
  4. Dr. Yuguang Ma3,
  5. Dr. Gregory J. Halder2,
  6. Prof. Dr. Perla B. Balbuena3,
  7. Prof. Dr. Hong-Cai Zhou1,*

Article first published online: 3 SEP 2012

DOI: 10.1002/anie.201202992

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 51, Issue 39, pages 9804–9808, September 24, 2012

Additional Information

How to Cite

Wriedt, M., Sculley, J. P., Yakovenko, A. A., Ma, Y., Halder, G. J., Balbuena, P. B. and Zhou, H.-C. (2012), Low-Energy Selective Capture of Carbon Dioxide by a Pre-designed Elastic Single-Molecule Trap . Angew. Chem. Int. Ed., 51: 9804–9808. doi: 10.1002/anie.201202992

Author Information

  1. 1

    Department of Chemistry, Texas A&M University, College Station, TX 77843 (USA) http://www.chem.tamu.edu/rgroup/zhou/

  2. 2

    X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439 (USA)

  3. 3

    Artie McFerrin Department of Chemical Engineering, Texas A&M University, College Station, TX 77843 (USA)

*Department of Chemistry, Texas A&M University, College Station, TX 77843 (USA) http://www.chem.tamu.edu/rgroup/zhou/

  1. †

    Funding was provided by the U.S. Department of Energy (DOE DE-SC0001015 and DE-AR0000073). M.W. acknowledges the Postdoc Programme of the German Academic Exchange Service (DAAD) for his financial support. Special thanks go to C. Näther from the University of Kiel (Germany) for the crystallographic help on PCN-200-syn and A. Callejas-Tovar who carried out the IAST calculations. Use of the Advanced Photon Source, an Office of Science User Facility operated for the U.S. Department of Energy (DOE) Office of Science by Argonne National Laboratory, was supported by the U.S. DOE under Contract No. DE-AC02-06CH11357. In this context we thank K. W. Chapman for her onsite help.

Publication History

  1. Issue published online: 19 SEP 2012
  2. Article first published online: 3 SEP 2012
  3. Manuscript Revised: 26 JUL 2012
  4. Manuscript Received: 18 APR 2012

Funded by

  • U.S. Department of Energy. Grant Numbers: DE-SC0001015, DE-AR0000073
  • DAAD
  • U.S. Department of Energy. Grant Number: DE-AC02-06CH11357

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Keywords:

  • CO2 capture;
  • metal–organic frameworks;
  • porous materials;
  • X-ray diffraction
Thumbnail image of graphical abstract

Single-molecule trap: Easy activation of the water-stable metal–organic framework PCN-200 provides a new route to low-energy selective CO2 capture through stimuli-responsive adsorption behavior. This elastic CO2 trapping effect was confirmed by single-component and binary gas-adsorption isotherms and crystallographic determination.

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