Communication

Microfluidic Synthesis of Palladium Nanocrystals Assisted by Supercritical CO2: Tailored Surface Properties for Applications in Boron Chemistry†

  1. Dr. Thomas Gendrineau1,2,
  2. Dr. Samuel Marre1,
  3. Dr. Michel Vaultier2,
  4. Dr. Mathieu Pucheault2,*,
  5. Dr. Cyril Aymonier1,*

Article first published online: 23 JUL 2012

DOI: 10.1002/anie.201203083

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 51, Issue 34, pages 8525–8528, August 20, 2012

Additional Information

How to Cite

Gendrineau, T., Marre, S., Vaultier, M., Pucheault, M. and Aymonier, C. (2012), Microfluidic Synthesis of Palladium Nanocrystals Assisted by Supercritical CO2: Tailored Surface Properties for Applications in Boron Chemistry . Angew. Chem. Int. Ed., 51: 8525–8528. doi: 10.1002/anie.201203083

Author Information

  1. 1

    CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr. Albert Schweitzer, 33608 Pessac (France)

  2. 2

    ISM, UMR CNRS 5255, Université Bordeaux 1, 351 Cours de la Libération, 33405 Talence (France)

*ISM, UMR CNRS 5255, Université Bordeaux 1, 351 Cours de la Libération, 33405 Talence (France)

  1. †

    The authors thank the GIS Advanced Materials in Aquitaine for financial support.

Publication History

  1. Issue published online: 14 AUG 2012
  2. Article first published online: 23 JUL 2012
  3. Manuscript Received: 22 APR 2012

Funded by

  • GIS Advanced Materials in Aquitaine

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Keywords:

  • boron;
  • cross-coupling;
  • heterogeneous catalysis;
  • nanostructures;
  • palladium
Thumbnail image of graphical abstract

On the surface: A library of organic–inorganic hybrid palladium nanocrystals was synthesized using continuous supercritical microfluidic technology. The nanocatalysts show moderate to excellent activities towards CAr[BOND]B and CAr[BOND]CAr bond-forming reactions, thus illustrating the relationship between surface properties and modulated catalytic activity.

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