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Visible-Light-Induced Photocatalytic Reductive Transformations of Organohalides


  • This work was supported by the Basic Research Laboratory (BRL) and Global Ph.D. Fellowship (GPF) programs of the National Research Foundation (NRF) funded by the Korean government. We thank Prof. Stefan Bernhard at Carniegie Mellon University and Jong-In Hong at Seoul National University for valuable suggestions, and Dr. Ik-Soo Shin and Yongjun Jeon for obtaining cyclic voltammograms.


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A photo opportunity: A visible-light-excited iridium catalyst delivers electrons from an amine to an organohalide. The electron transfer then induces reductive scission of the carbon–halogen bond, generating the corresponding alkyl, alkenyl, and aryl radical that can undergo cyclization and hydrodehalogenation reactions.

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