Thanks are expressed to COST Action CM0802 “PhoSciNet” and MIUR (Italy) through PRIN2009 for supporting this research activity.
Iodine Activation of Coordinated White Phosphorus: Formation and Transformation of 1,3-Dihydride-2-iodidecyclotetraphosphane†
Article first published online: 18 JUL 2012
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 51, Issue 34, pages 8628–8631, August 20, 2012
How to Cite
Barbaro, P., Bazzicalupi, C., Peruzzini, M., Seniori Costantini, S. and Stoppioni, P. (2012), Iodine Activation of Coordinated White Phosphorus: Formation and Transformation of 1,3-Dihydride-2-iodidecyclotetraphosphane . Angew. Chem. Int. Ed., 51: 8628–8631. doi: 10.1002/anie.201203908
- Issue published online: 14 AUG 2012
- Article first published online: 18 JUL 2012
- Manuscript Received: 21 MAY 2012
- COST Action. Grant Number: CM0802
- MIUR. Grant Number: PRIN2009
Double stabilization: Previously unknown polyphosphorus compounds are obtained by activation of white phosphorus (P4) coordinated between two CpRu(PPh3)2 moieties with iodine, and subsequent hydrolysis. The polyphosphorus compounds (P4H2I, P4H2, P3H5; see scheme, Cp=cyclopentadienyl) are all stabilized by coordination to two ruthenium centers.