Communication

Iodine Activation of Coordinated White Phosphorus: Formation and Transformation of 1,3-Dihydride-2-iodidecyclotetraphosphane†

  1. Dr. Pierluigi Barbaro1,
  2. Dr. Carla Bazzicalupi2,
  3. Dr. Maurizio Peruzzini1,
  4. Dr. Stefano Seniori Costantini2,
  5. Prof. Dr. Piero Stoppioni2,*

Article first published online: 18 JUL 2012

DOI: 10.1002/anie.201203908

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 51, Issue 34, pages 8628–8631, August 20, 2012

Additional Information

How to Cite

Barbaro, P., Bazzicalupi, C., Peruzzini, M., Seniori Costantini, S. and Stoppioni, P. (2012), Iodine Activation of Coordinated White Phosphorus: Formation and Transformation of 1,3-Dihydride-2-iodidecyclotetraphosphane . Angew. Chem. Int. Ed., 51: 8628–8631. doi: 10.1002/anie.201203908

Author Information

  1. 1

    ICCOM CNR via Madonna del Piano,10, 50019 Sesto Fiorentino, Firenze (Italy)

  2. 2

    Dipartimento di Chimica, Università di Firenze via della Lastruccia,3, 50019 Sesto Fiorentino, Firenze (Italy)

*Dipartimento di Chimica, Università di Firenze via della Lastruccia,3, 50019 Sesto Fiorentino, Firenze (Italy)

  1. †

    Thanks are expressed to COST Action CM0802 “PhoSciNet” and MIUR (Italy) through PRIN2009 for supporting this research activity.

Publication History

  1. Issue published online: 14 AUG 2012
  2. Article first published online: 18 JUL 2012
  3. Manuscript Received: 21 MAY 2012

Funded by

  • COST Action. Grant Number: CM0802
  • MIUR. Grant Number: PRIN2009

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (620K)

Keywords:

  • hydrolysis;
  • iodine;
  • phosphorus;
  • polyphosphanes;
  • ruthenium
Thumbnail image of graphical abstract

Double stabilization: Previously unknown polyphosphorus compounds are obtained by activation of white phosphorus (P4) coordinated between two CpRu(PPh3)2 moieties with iodine, and subsequent hydrolysis. The polyphosphorus compounds (P4H2I, P4H2, P3H5; see scheme, Cp=cyclopentadienyl) are all stabilized by coordination to two ruthenium centers.

View Full Article with Supporting Information (HTML) Get PDF (620K)