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Keywords:

  • carbon dioxide fixation;
  • confined conditions;
  • molecular recognition;
  • polyoxometalates;
  • porous capsules
Thumbnail image of graphical abstract

30 receptors in waiting position: In the porous (pentagon)12(linker)30-type molybdenum oxide capsule (see picture), the 30 positively charged linkers (five unsaturated shown for illustration in green, the others contain CO32− ligands) can act as receptors for neutral and negatively charged ligands. Bubbling CO2 into the solution containing the acetate-type capsules leads to the upload of CO2 based on 30 coordinated CO32− ligands.