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Inside Back Cover: Electrochemical Mapping Reveals Direct Correlation between Heterogeneous Electron-Transfer Kinetics and Local Density of States in Diamond Electrodes (Angew. Chem. Int. Ed. 28/2012)

  1. Hollie V. Patten1,
  2. Katherine E. Meadows1,2,
  3. Dr. Laura A. Hutton1,
  4. James G. Iacobini1,
  5. Dario Battistel3,
  6. Kim McKelvey1,2,
  7. Dr. Alexander W. Colburn1,
  8. Dr. Mark E. Newton4,
  9. Prof. Julie V. Macpherson1,*,
  10. Prof. Patrick R. Unwin1,*

Article first published online: 3 JUL 2012

DOI: 10.1002/anie.201204563

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 51, Issue 28, page 7049, July 9, 2012

Additional Information

How to Cite

Patten, H. V., Meadows, K. E., Hutton, L. A., Iacobini, J. G., Battistel, D., McKelvey, K., Colburn, A. W., Newton, M. E., Macpherson, J. V. and Unwin, P. R. (2012), Inside Back Cover: Electrochemical Mapping Reveals Direct Correlation between Heterogeneous Electron-Transfer Kinetics and Local Density of States in Diamond Electrodes (Angew. Chem. Int. Ed. 28/2012). Angew. Chem. Int. Ed., 51: 7049. doi: 10.1002/anie.201204563

Author Information

  1. 1

    Department of Chemistry, University of Warwick, Coventry, CV4 7AL (UK)

  2. 2

    MOAC Doctoral Training Centre, University of Warwick, Coventry, CV4 7AL (UK)

  3. 3

    Department of Physical Chemistry, University of Venice, CalleLarga, S. Marta, 2137, 30123 Venice (Italy)

  4. 4

    Department of Physics, University of Warwick, Coventry, CV5 7LL (UK)

*Department of Chemistry, University of Warwick, Coventry, CV4 7AL (UK)

Publication History

  1. Issue published online: 4 JUL 2012
  2. Article first published online: 3 JUL 2012

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Keywords:

  • carbon;
  • electrochemistry;
  • electron transfer;
  • kinetics;
  • scanning electrochemical microscopy
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A Multi-Microscopy Approach has allowed electrochemical reaction rates to be linked to the corresponding dopant levels in polycrystalline boron-doped diamond electrodes. In their Communication on page 7002 ff., P. R. Unwin, J. V. Macpherson, et al. combine high-resolution electrochemical imaging, micro-Raman, and electron-microscopy data to demonstrate that spatially heterogeneous electron-transfer kinetics correlate directly with the local density of electronic states.

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