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Inside Back Cover: Copper Catalyst Activation Driven by Photoinduced Electron Transfer: A Prototype Photolatent Click Catalyst (Angew. Chem. Int. Ed. 29/2012)
Article first published online: 6 JUL 2012
DOI: 10.1002/anie.201204564
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Harmand, L., Cadet, S., Kauffmann, B., Scarpantonio, L., Batat, P., Jonusauskas, G., McClenaghan, N. D., Lastécouères, D. and Vincent, J.-M. (2012), Inside Back Cover: Copper Catalyst Activation Driven by Photoinduced Electron Transfer: A Prototype Photolatent Click Catalyst (Angew. Chem. Int. Ed. 29/2012). Angew. Chem. Int. Ed., 51: 7333. doi: 10.1002/anie.201204564
Publication History
- Issue published online: 11 JUL 2012
- Article first published online: 6 JUL 2012
Keywords:
- click chemistry;
- copper;
- Huisgen cycloaddition;
- photocontrolled catalysts;
- photolatent catalysts
As light changes night (yin) into day (yang), irradiation of the click-inactive copper(II) tren ketoprofenate complex triggers an efficient photoinduced electron-transfer process to provide a highly active copper(I) tren click catalyst. In their Communication on page 7137 ff., J.-M. Vincent et al. also show that by simply introducing air into the reaction medium the catalysis can be switched off, and then on again by bubbling argon followed by irradiation.