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Gold in Total Synthesis: Alkynes as Carbonyl Surrogates
Article first published online: 13 JUL 2012
DOI: 10.1002/anie.201204598
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Issue
Angewandte Chemie International Edition
Volume 51, Issue 36, pages 8933–8935, September 3, 2012
Additional Information
How to Cite
Brenzovich, W. E. (2012), Gold in Total Synthesis: Alkynes as Carbonyl Surrogates. Angew. Chem. Int. Ed., 51: 8933–8935. doi: 10.1002/anie.201204598
Publication History
- Issue published online: 28 AUG 2012
- Article first published online: 13 JUL 2012
- Manuscript Received: 13 JUN 2012
- Abstract
- Article
- References
- Cited By
Keywords:
- cyclization;
- gold;
- homogeneous catalysis;
- total synthesis;
- synthetic methods
Fields of gold: Recent developments in the field of gold catalysis, using an alkyne as a carbonyl equivalent is becoming an important chemical transformation, thus providing flexibility in synthetic planning of complex and sensitive natural products. Understanding of the reaction and new catalyst designs are providing new conditions that are amenable for late-stage synthetic intermediates.