We thank NSF for support of this work (J.L.A.) and NIBIB for training grant T21 EB004822 (A.V.M.). This work utilized facilities supported in part by the NSF under Agreement No. DMR-0944772 (S.R.K.).
Solution-Phase and Magnetic Approach towards Understanding Iron Gall Ink-like Nanoassemblies†
Article first published online: 13 AUG 2012
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 51, Issue 37, pages 9263–9266, September 10, 2012
How to Cite
Kumari, H., Kline, S. R., Dennis, C. L., Mossine, A. V., Paul, R. L., Deakyne, C. A. and Atwood, J. L. (2012), Solution-Phase and Magnetic Approach towards Understanding Iron Gall Ink-like Nanoassemblies . Angew. Chem. Int. Ed., 51: 9263–9266. doi: 10.1002/anie.201204776
- Issue published online: 5 SEP 2012
- Article first published online: 13 AUG 2012
- Manuscript Received: 19 JUN 2012
- NIBIB. Grant Number: T21 EB004822
- magnetic properties;
- small-angle neutron scattering (SANS);
- supramolecular chemistry
Metal-containing tubes: The structures of several iron-containing C-methylpyrogallolarene (PgC1) nanoassemblies were studied in both the solid and solution phases. The nanoassemblies have a tubular architecture with the iron as part of the framework (see picture; gray C, red O, turquoise/blue Fe), and magnetic analysis suggests a canted or spiral arrangement of the iron centers.