These authors contributed equally to this work.
A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal–Organic Frameworks†
Article first published online: 9 AUG 2012
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 51, Issue 37, pages 9267–9271, September 10, 2012
How to Cite
Guillerm, V., Ragon, F., Dan-Hardi, M., Devic, T., Vishnuvarthan, M., Campo, B., Vimont, A., Clet, G., Yang, Q., Maurin, G., Férey, G., Vittadini, A., Gross, S. and Serre, C. (2012), A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal–Organic Frameworks . Angew. Chem. Int. Ed., 51: 9267–9271. doi: 10.1002/anie.201204806
This work has been performed within the frame of the ANR “NOMAC” (ANR-06-CO2-008) and the Macademia European Community’s Seventh Framework Program (FP7/2007-2013) under grant agreement n° 228862“. Farid Nouar is thanked for this help with TOPOS and G. Le Bars for some IR measurements. Diamond Synchrotron Beamline I11 for part of the XRPD data collection.
- Issue published online: 5 SEP 2012
- Article first published online: 9 AUG 2012
- Manuscript Received: 19 JUN 2012
- ANR “NOMAC”
- Macademia European Community’s Seventh Framework Program. Grant Number: 228862
- infrared spectroscopy;
- metal–organic framework;
- modeling studies;
Brolly good MOFs: A new series of hydrophobic isoreticular porous Zr oxide dicarboxylate MOFs have been prepared (see picture, Zr blue polyhedra, O red, C black). They have a one-dimensional pore system, a rare combination of Lewis acidity and hydrophobic character, and a higher hydrothermal and mechanical stability than their UiO MOF polymorph counterparts.