A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal–Organic Frameworks

Authors

  • Dr. V. Guillerm,

    1. Institut Lavoisier,UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, 45 avenue des Etats-Unis, 78035 Versailles (France)
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    • These authors contributed equally to this work.

  • F. Ragon,

    1. Institut Lavoisier,UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, 45 avenue des Etats-Unis, 78035 Versailles (France)
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    • These authors contributed equally to this work.

  • Dr. M. Dan-Hardi,

    1. Institut Lavoisier,UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, 45 avenue des Etats-Unis, 78035 Versailles (France)
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  • Dr. T. Devic,

    1. Institut Lavoisier,UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, 45 avenue des Etats-Unis, 78035 Versailles (France)
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  • Dr. M. Vishnuvarthan,

    1. Laboratoire Catalyse et Spectrochimie, Ensicaen, Université de Caen, CNRS, 6 Bd du Maréchal Juin, 14050 Caen (France)
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  • Dr. B. Campo,

    1. Laboratoire Catalyse et Spectrochimie, Ensicaen, Université de Caen, CNRS, 6 Bd du Maréchal Juin, 14050 Caen (France)
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  • Dr. A. Vimont,

    1. Laboratoire Catalyse et Spectrochimie, Ensicaen, Université de Caen, CNRS, 6 Bd du Maréchal Juin, 14050 Caen (France)
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  • Dr. G. Clet,

    1. Laboratoire Catalyse et Spectrochimie, Ensicaen, Université de Caen, CNRS, 6 Bd du Maréchal Juin, 14050 Caen (France)
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  • Prof. Q. Yang,

    1. Institut Charles Gerhardt, UMR CNRS 5253, ENSCM - CNRS - UMI - UMII, Université Montpellier 2, 34095 Montpellier cedex 05 (France)
    2. State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029 (China)
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  • Prof. G. Maurin,

    1. Institut Charles Gerhardt, UMR CNRS 5253, ENSCM - CNRS - UMI - UMII, Université Montpellier 2, 34095 Montpellier cedex 05 (France)
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  • Prof. G. Férey,

    1. Institut Lavoisier,UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, 45 avenue des Etats-Unis, 78035 Versailles (France)
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  • Dr. A. Vittadini,

    1. ISTM-CNR, Dipartimento di Scienze Chimiche and INSTM, UdR Padova, Università degli Studi di Padova via Marzolo 1, 35131 Padova (Italy)
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  • Dr. S. Gross,

    1. ISTM-CNR, Dipartimento di Scienze Chimiche and INSTM, UdR Padova, Università degli Studi di Padova via Marzolo 1, 35131 Padova (Italy)
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  • Dr. Christian Serre

    Corresponding author
    1. Institut Lavoisier,UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, 45 avenue des Etats-Unis, 78035 Versailles (France)
    • Institut Lavoisier,UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, 45 avenue des Etats-Unis, 78035 Versailles (France)
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  • This work has been performed within the frame of the ANR “NOMAC” (ANR-06-CO2-008) and the Macademia European Community’s Seventh Framework Program (FP7/2007-2013) under grant agreement n° 228862“. Farid Nouar is thanked for this help with TOPOS and G. Le Bars for some IR measurements. Diamond Synchrotron Beamline I11 for part of the XRPD data collection.

Abstract

original image

Brolly good MOFs: A new series of hydrophobic isoreticular porous Zr oxide dicarboxylate MOFs have been prepared (see picture, Zr blue polyhedra, O red, C black). They have a one-dimensional pore system, a rare combination of Lewis acidity and hydrophobic character, and a higher hydrothermal and mechanical stability than their UiO MOF polymorph counterparts.

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