This work was supported by the DFG-funded transregional collaborative research center SFB/TRR 88 “3MET”. The author also thanks Prof. Annie K. Powell for her support.
Differentiation of Highly Anisotropic TbIII and DyIII with 57Fe Mössbauer Spectroscopy†
Article first published online: 3 SEP 2012
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 51, Issue 39, pages 9922–9925, September 24, 2012
How to Cite
Mereacre, V. (2012), Differentiation of Highly Anisotropic TbIII and DyIII with 57Fe Mössbauer Spectroscopy . Angew. Chem. Int. Ed., 51: 9922–9925. doi: 10.1002/anie.201204838
- Issue published online: 19 SEP 2012
- Article first published online: 3 SEP 2012
- Manuscript Received: 20 JUN 2012
- SFB/TRR 88 “3MET”
- Mössbauer spectroscopy
Using 57Fe Mössbauer spectroscopy, three examples of coordination compounds with different topologies containing FeIII and LnIII ions (DyIII and TbIII; see diagram; insets: clusters cores) were analyzed. In the same crystal field environment, Dy and Tb ions show different degrees of anisotropy, which can be qualitatively detected using an indirect method.