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Keywords:

  • methane;
  • nickel;
  • solid solutions;
  • steam reforming;
  • XAFS
Thumbnail image of graphical abstract

Breaking news: A unique discontinuous property and an active phase of Ni/ordered Ce2Zr2Ox (x=7–8) solid-solution catalysts were observed during methane steam reforming. The catalytic performance of Ni/Ce2Zr2Ox strongly depended on the phase and oxygen content of the Ce2Zr2Ox support.