We thank the Fonds der Chemischen Industrie, the European Research Council (ERC), and the Deutsche Forschungsgemeinschaft (SFB 749) for financial support. We also thank Evonik Industries AG (Hanau), and BASF AG (Ludwigshafen) for generous donations of chemicals.
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Communication
InCl3-Catalyzed Synthesis of 1,2-Dimetallic Compounds by Direct Insertion of Aluminum or Zinc Powder†
Article first published online: 5 SEP 2012
DOI: 10.1002/anie.201205169
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Issue
Angewandte Chemie International Edition
Volume 51, Issue 39, pages 9926–9930, September 24, 2012
Additional Information
How to Cite
Blümke, T. D., Klatt, T., Koszinowski, K. and Knochel, P. (2012), InCl3-Catalyzed Synthesis of 1,2-Dimetallic Compounds by Direct Insertion of Aluminum or Zinc Powder . Angew. Chem. Int. Ed., 51: 9926–9930. doi: 10.1002/anie.201205169
- †
Publication History
- Issue published online: 19 SEP 2012
- Article first published online: 5 SEP 2012
- Manuscript Received: 2 JUL 2012
Funded by
- Fonds der Chemischen Industrie
- European Research Council
- ERC
- Deutsche Forschungsgemeinschaft. Grant Number: SFB 749
- Evonik
- BASF
Keywords:
- 1,2-dimetallic compounds;
- aluminum;
- cross-coupling;
- indium;
- zinc
In-sertion of metal: Catalytic amounts of InCl3 allow the insertion of aluminum and zinc into aromatic 1,2-dibromides or 1,2-bromotriflates (see scheme). These 1,2-dimetallic species can undergo Cu or Pd-catalyzed acylations, allylations, or cross-couplings.