Production of p-Xylene from Biomass by Catalytic Fast Pyrolysis Using ZSM-5 Catalysts with Reduced Pore Openings

Authors


  • This work was supported as part of the Catalysis Center for Energy Innovation, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under award number DE-SC0001004. G.W.H. is a shareholder and chairman of the Scientific Advisory Board of Anellotech.

Abstract

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Pores for thought: Chemical liquid deposition of silica onto ZSM-5 catalysts led to smaller pore openings that resulted in >90 % selectivity for p-xylene over the other xylenes in the catalytic fast pyrolysis of furan and 2-methylfuran (see scheme). The p-xylene selectivity increased from 51 % with gallium spray-dried ZSM-5 to 72 % with a pore-mouth-modified catalyst in the pyrolysis of pine wood.

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