This work was supported by the Deutsche Forschungsgemeinschaft.
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Communication
Metal-Mediated Synthesis of 1,4-Di-tert-butyl-1,4-azaborine†
Article first published online: 5 SEP 2012
DOI: 10.1002/anie.201205795
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Issue
1521-3773/asset/cover.gif?v=1&s=412bc65bdcb3f0e34a94f27c1c13e908726694d4 "Angewandte Chemie International Edition")
Angewandte Chemie International Edition
Volume 51, Issue 40, pages 10034–10037, October 1, 2012
Additional Information
How to Cite
Braunschweig, H., Damme, A., Jimenez-Halla, J. O. C., Pfaffinger, B., Radacki, K. and Wolf, J. (2012), Metal-Mediated Synthesis of 1,4-Di-tert-butyl-1,4-azaborine . Angew. Chem. Int. Ed., 51: 10034–10037. doi: 10.1002/anie.201205795
- †
Publication History
- Issue published online: 26 SEP 2012
- Article first published online: 5 SEP 2012
- Manuscript Received: 23 JUL 2012
Funded by
- Deutsche Forschungsgemeinschaft
Keywords:
- acetylene;
- boron;
- boron heterocycles;
- cyclization;
- rhodium
Completing the set: Although 1,2-azaborine is known, little is known about the 1,3- and 1,4-analogues. Now a simple, controlled synthesis of 1,2-di-tert-butyl-1,2-azaborine from acetylene and di-tert-butyliminoborane has been achieved by a metal-mediated formal [2+2+2] cycloaddition reaction. A 1,2-azaborete pianostool complex was identified as an reaction intermediate.