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Weak Te,Te Interactions through the Looking Glass of NMR Spin–Spin Coupling†

  1. Prof. Michael Bühl1,*,
  2. Dr. Fergus R. Knight1,
  3. Anezka Křístková2,
  4. Dr. Irina Malkin Ondík3,
  5. Dr. Olga L. Malkina2,
  6. Rebecca A. M. Randall1,
  7. Prof. Alexandra M. Z. Slawin1,
  8. Prof. J. Derek Woollins1

Article first published online: 23 JAN 2013

DOI: 10.1002/anie.201205998

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 52, Issue 9, pages 2495–2498, February 25, 2013

Additional Information

How to Cite

Bühl, M., Knight, F. R., Křístková, A., Malkin Ondík, I., Malkina, O. L., Randall, R. A. M., Slawin, A. M. Z. and Woollins, J. D. (2013), Weak Te,Te Interactions through the Looking Glass of NMR Spin–Spin Coupling . Angew. Chem. Int. Ed., 52: 2495–2498. doi: 10.1002/anie.201205998

Author Information

  1. 1

    EaStCHEM School of Chemistry, University of St. Andrews, North Haugh, St. Andrews, Fife KY16 9ST (UK)

  2. 2

    Slovak Academy of Sciences, Institute of Inorganic Chemistry, 84536 Bratislava (Slovakia)

  3. 3

    Faculty of Mathematics, Physics and Informatics, Comenius University, Bratislava, 842 48 Bratislava (Slovakia)

*EaStCHEM School of Chemistry, University of St. Andrews, North Haugh, St. Andrews, Fife KY16 9ST (UK)

  1. †

    This work was supported by the School of Chemistry and by EaStChem via the EaStChem Research Computing facility maintained by Dr. H. Früchtl, and by Slovak grant agencies VEGA (grant 2/0079/09) and APVV (grant LPP-0326-09). We thank Prof. Bernd Wrackmeyer for suggesting the 123Te NMR experiments and Dr. Vladimir G. Malkin for helpful discussions.

Publication History

  1. Issue published online: 19 FEB 2013
  2. Article first published online: 23 JAN 2013
  3. Manuscript Revised: 14 NOV 2012
  4. Manuscript Received: 26 JUL 2012

Funded by

  • Slovak grant agencies VEGA. Grant Number: 2/0079/09
  • APVV. Grant Number: LPP-0326-09

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Keywords:

  • naphthalenes;
  • quantum-chemical computation;
  • tellurium;
  • through-bond interactions;
  • through-space interactions
Thumbnail image of graphical abstract

Across the bay: J(125Te,125Te) spin–spin coupling is a highly sensitive probe into the electronic and geometric structure of 1,8-peri-substituted naphthalene tellurium derivatives. The coupling is related to the onset of multicenter bonding in these systems.

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