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[([TRIPLE BOND]SiO)TaVCl2Me2]: A Well-Defined Silica-Supported Tantalum(V) Surface Complex as Catalyst Precursor for the Selective Cocatalyst-Free Trimerization of Ethylene†

  1. Yin Chen1,
  2. Emmanuel Callens1,
  3. Edy Abou-Hamad1,
  4. Nicolas Merle2,
  5. Andrew J. P. White3,
  6. Mostafa Taoufik2,
  7. Christophe Copéret2,5,
  8. Erwan Le Roux4,*,
  9. Jean-Marie Basset1,*

Article first published online: 22 OCT 2012

DOI: 10.1002/anie.201206272

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 51, Issue 47, pages 11886–11889, November 19, 2012

Additional Information

How to Cite

Chen, Y., Callens, E., Abou-Hamad, E., Merle, N., White, A. J. P., Taoufik, M., Copéret, C., Le Roux, E. and Basset, J.-M. (2012), [([TRIPLE BOND]SiO)TaVCl2Me2]: A Well-Defined Silica-Supported Tantalum(V) Surface Complex as Catalyst Precursor for the Selective Cocatalyst-Free Trimerization of Ethylene . Angew. Chem. Int. Ed., 51: 11886–11889. doi: 10.1002/anie.201206272

Author Information

  1. 1

    KAUST Catalysis Center, King Abdullah University of Science and Technology, Thuwal 23955-6900 (Kingdom of Saudi Arabia)

  2. 2

    Chimie Organometallique de Surface/Laboratoire de Chimie, Polymeres et Procedes UMR-C2P2-5265CNRS/ESCPE-Lyon/UCBL) ESCPE Lyon, F-308-43 Boulevard du 11 Novembre 1918, F-69616, Villeurbanne Cedex (France)

  3. 3

    Department of Chemistry, Imperial College London, Exhibition Road, London SW7 2AZ, England (UK)

  4. 4

    Department of Chemistry, University of Bergen, Realfagbygget, Allegaten 41, 5007, Bergen (Norway)

  5. 5

    Department of Chemistry, ETH Zurich, HCI H 229 Wolfgang-Pauli-Strasse 10, 8093, Zurich (Switzerland)

*Department of Chemistry, University of Bergen, Realfagbygget, Allegaten 41, 5007, Bergen (Norway)

  1. †

    We are indebted to Prof. Lyndon Emsley for his enthusiastic discussion and suggestions. The work is supported by KAUST and SABIC.

Publication History

  1. Issue published online: 14 NOV 2012
  2. Article first published online: 22 OCT 2012
  3. Manuscript Received: 5 AUG 2012

Funded by

  • KAUST
  • SABIC

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