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Keywords:

  • NMR spectroscopy;
  • palladium;
  • peptides;
  • supramolecular chemistry;
  • X-ray diffraction
Thumbnail image of graphical abstract

Metal-mediated secondary structures of peptide-based foldamers were constructed using artificial backbone-coordinative oxime peptides. Complexation of the peptides with PdII afforded several mononuclear and dinuclear secondary structures such as helices and hairpins as confirmed by single-crystal XRD and NMR analyses (see picture).