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Keywords:

  • fluorinated ligands;
  • phosphane ligands;
  • photochemistry;
  • radical reactions;
  • synthetic methods
Thumbnail image of graphical abstract

A ‘F'lurry of activity: The title reaction provides a convenient procedure for direct synthesis of perfluoroalkylated phosphines. The synthesized phosphine n-C10F21PPh2 forms a complex with palladium(II) to give 1 and several runs of coupling reactions are attained with n-C10F21PPh2 by using a fluorous/organic biphasic system.